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Tricarbonylbis-(triphenyl-phosphane-?P)iridium(I) hexa-fluoridophosphate methanol monosolvate.

ABSTRACT: In the title compound, [Ir(C(18)H(15)P)(2)(CO)(3)]PF(6)·CH(3)OH, the Ir(I) atom is coordinated by two triphenyl-phosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C-Ir-C angles range from 115.45?(9) to 126.42?(10)°. The small deviations from the ideal tetra-hedral geometry around the P atoms are illustrated by C-P-C angles ranging from 104.08?(9) to 106.46?(9)°. In the crystal, the mol-ecules are linked by weak C-H?F, C-H?O and C-H?? inter-actions.

SUBMITTER: Engelbrecht I

PROVIDER: S-EPMC3435607 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Tricarbonylbis-(triphenyl-phosphane-κP)iridium(I) hexa-fluoridophosphate methanol monosolvate.

Engelbrecht Ilana I Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9

In the title compound, [Ir(C(18)H(15)P)(2)(CO)(3)]PF(6)·CH(3)OH, the Ir(I) atom is coordinated by two triphenyl-phosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C-Ir-C angles range from 115.45 (9) to 126.42 (10)°. The small deviations from the ideal tetra-hedral geometry around the P atoms are illustrated by C-P-C angles ranging from 104.08 (9) to 106.46 (9)°. In the crystal, the mol-ecules are linked by we ...[more]

PMID: 22969480

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