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Bis(2,2'-bipyrimidine-?(2)N(1),N(1'))palladium(II) bis-(tetra-fluoro-borate) acetonitrile monosolvate.

ABSTRACT: The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2'-bipyrimidine (bpm) in MeCN-CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra-hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C-H?N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C-H?F and C-H?N inter-actions involving the tetra-fluoro-borate anions and acetonitrile mol-ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

SUBMITTER: Duong A

PROVIDER: S-EPMC3515108 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyrimidine-κ(2)N(1),N(1'))palladium(II) bis-(tetra-fluoro-borate) acetonitrile monosolvate.

Duong Adam A Wuest James D JD Maris Thierry T

Acta crystallographica. Section E, Structure reports online 20121013 Pt 11

The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2'-bipyrimidine (bpm) in MeCN-CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra-hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C-H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C-H⋯F and C-H⋯N inter ...[more]

PMID: 23284335

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