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Cis-Bis(2,2'-bipyrimidine-?N,N)dibromidomanganese(II) nitro-methane monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro-methane solvent mol-ecule, the complete mol-ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a distorted cis-Br(2)N(4) octa-hedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br(-) ions. There are intra- and inter-molecular C-H?Br and C-H?N contacts.

SUBMITTER: Ha K 

PROVIDER: S-EPMC3100068 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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cis-Bis(2,2'-bipyrimidine-κN,N)dibromidomanganese(II) nitro-methane monosolvate.

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro-methane solvent mol-ecule, the complete mol-ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a distorted cis-Br(2)N(4) octa-hedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br(-) ions. There are intra- and inter-molecular C-H⋯Br and C-H⋯N c  ...[more]

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