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Bis[4-(4-bromophenylimino-?N)pent-2-en-2-olato-?O]copper(II).

ABSTRACT: In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter-molecular C-H?O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis. The mol-ecules pack in layers along the diagonal of the bc plane.

SUBMITTER: Bungu PS

PROVIDER: S-EPMC3515125 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II).

Bungu Paul S E PS Schutte Marietjie M Steyl G G

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis. The mol-ecules pack in layers along the diagonal of the bc plane. ...[more]

PMID: 23284352

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Bis(5-chloroquinolin-8-olato)-bis(pyridine)-cobalt(II) as new catalytic material.

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