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ABSTRACT:
SUBMITTER: Ahmad S
PROVIDER: S-EPMC3515146 | biostudies-literature | 2012 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121024 Pt 11
The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry. The crystal structure is stabilized by N-H⋯I hydrog ...[more]