Unknown

Dataset Information

0

(+)-(1S,5R,6R)-6-[(S)-1-Hy-droxy-2-(meth-oxy-meth-yloxy)eth-yl]-1-methyl-3-trichloro-methyl-2-aza-4,7-dioxa-bicyclo-[3.3.0]oct-2-en-8-one.

ABSTRACT: In the title compound, C(11)H(14)Cl(3)NO(6), the fused five-membered oxazoline and tetra-hydro-furan rings are essentially planar with maximum deviations of 0.069?(1) and 0.031?(1)?Å, respectively, and make a dihedral angle of 64.23?(11)° with each other. In the crystal, mol-ecules are linked by O-H?O and C-H?O hydrogen bonds, forming chains along the b-axis direction. Further C-H?O hydrogen bonds are observed between the chains.

SUBMITTER: Oishi T 

PROVIDER: S-EPMC3515276 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(+)-(1S,5R,6R)-6-[(S)-1-Hy-droxy-2-(meth-oxy-meth-yloxy)eth-yl]-1-methyl-3-trichloro-methyl-2-aza-4,7-dioxa-bicyclo-[3.3.0]oct-2-en-8-one.

Oishi Takeshi T   Oishi Hiroki H   Tsuzaki Syun S   Sato Takaaki T   Chida Noritaka N  

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

In the title compound, C(11)H(14)Cl(3)NO(6), the fused five-membered oxazoline and tetra-hydro-furan rings are essentially planar with maximum deviations of 0.069 (1) and 0.031 (1) Å, respectively, and make a dihedral angle of 64.23 (11)° with each other. In the crystal, mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains. ...[more]

Similar Datasets

Unknown (1S,4S,5S,8R)-8-Nitro-oxy-2,6-dioxa-bicyclo-[3.3.0]octan-4-yl 3,4,5-triacetoxy-benzoate.
| S-EPMC2970955 | biostudies-literature
Unknown 4,7-Diphenyl-2,9-bis-(trichloro-meth-yl)-1,10-phenanthroline.
| S-EPMC2980224 | biostudies-literature
Unknown (1S*,4'S*,5R*)-1-Isobutyl-5-meth-oxy-2',3-dimethyl-4,6-dioxa-2-aza-spiro-[bicyclo-[3.2.0]hept-2-ene-7,4'-isoquinoline]-1',3'(2'H,4'H)-dione.
| S-EPMC3089195 | biostudies-literature
Unknown (1S*,5R*)-9-Phenyl-9-aza-bicyclo-[3.3.1]nonan-3-one.
| S-EPMC3379287 | biostudies-literature
Unknown (1S,5R)-1-(4-Fluoro-phen-yl)-3-azonia-bicyclo-[3.1.0]hexane chloride.
| S-EPMC2968785 | biostudies-literature
Unknown (1S,5R)-1-(3,4-Dichloro-phen-yl)-3-oxa-bicyclo-[3.1.0]hexan-2-one.
| S-EPMC2968819 | biostudies-literature
Unknown (1R*,2R*,4S*,5R*,6R*,8S*)-4,8-Dimethyl-2,6-diphenyl-bicyclo-[3.3.1]nonane-2,6-diol.
| S-EPMC2968924 | biostudies-literature
Unknown (1S*,4'S*,5R*)-1-Isopropyl-5-meth-oxy-2',3-dimethyl-4,6-dioxa-2-aza-spiro-[bicyclo-[3.2.0]hept-2-ene-7,4'-isoquinoline]-1',3'(2'H,4'H)-dione.
| S-EPMC3089152 | biostudies-other
Unknown (1S,4S,5S,6R)-6-(4-Bromo-phen-yl)-5-nitro-bicyclo-[2.2.2]octan-2-one.
| S-EPMC2968281 | biostudies-literature
Unknown (1R,3R,4R,6S)-4-(7-Meth-oxy-2-oxo-2H-chromen-6-yl)-1-methyl-3,6-dioxa-bicyclo-[3.1.0]hexan-2-yl acetate.
| S-EPMC3589005 | biostudies-literature