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Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100.

ABSTRACT: Triton(®) X-100 (poly(ethylene glycol) tert-octylphenyl ether) was (meth)acrylated and polymerized in the absence and presence of randomly methylated ?-cyclodextrin (RAMEB-CD). Triton(®)-polymers that were polymerized with RAMEB-CD in water were compared with polymers that were synthesized in organic solvents after the addition of RAMEB-CD. The polymers were characterized by (1)H NMR and FTIR spectroscopy, matrix-assisted laser desorption ionization mass spectrometry (MALDI-TOF MS), dynamic light scattering (DLS), gel-permeation chromatography (GPC) and turbidity measurements. Additionally, the viscosity change of the methacrylic homopolymer with RAMEB-CD was evaluated.

SUBMITTER: Kemnitz M

PROVIDER: S-EPMC3555431 | biostudies-literature | 2012

REPOSITORIES: biostudies-literature

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Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100.

Kemnitz Melanie M Ritter Helmut H

Beilstein journal of organic chemistry 20121213

Triton(®) X-100 (poly(ethylene glycol) tert-octylphenyl ether) was (meth)acrylated and polymerized in the absence and presence of randomly methylated β-cyclodextrin (RAMEB-CD). Triton(®)-polymers that were polymerized with RAMEB-CD in water were compared with polymers that were synthesized in organic solvents after the addition of RAMEB-CD. The polymers were characterized by (1)H NMR and FTIR spectroscopy, matrix-assisted laser desorption ionization mass spectrometry (MALDI-TOF MS), dynamic ligh ...[more]

PMID: 23378858

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