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2-(4-Sulfamoylphen-yl)hydrazin-1-ium chloride.

ABSTRACT: The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(-), is twisted out of the plane of the benzene ring to which it is attached [N-N-C-C torsion angle = 25.9?(2)°] and the amino group is almost perpendicular to the benzene ring [N-S-C-C torsion angle = 88.71?(16)°]. In the crystal, the cations are linked by N-H?O hydrogen bonds and ?-? inter-actions [ring centroid distance = 3.7280?(11)?Å], forming layers in the bc plane that are connected by N-H?Cl hydrogen bonds.

SUBMITTER: Asiri AM

PROVIDER: S-EPMC3344085 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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2-(4-Sulfamoylphen-yl)hydrazin-1-ium chloride.

Asiri Abdullah M AM Faidallah Hassan M HM Alamry Khalid A KA Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120321 Pt 4

The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(-), is twisted out of the plane of the benzene ring to which it is attached [N-N-C-C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N-S-C-C torsion angle = 88.71 (16)°]. In the crystal, the cations are linked by N-H⋯O hydrogen bonds and π-π inter-actions [ring centroid distance = 3.7280 (11) Å], forming layers in the bc plane that are connected by N-H⋯Cl hydrogen bonds. ...[more]

PMID: 22606088

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