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Bis(butane-1,4-diammonium) di-?-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate.

ABSTRACT: The title compound, (C4H14N2)2[Mo2O4F6]·H2O, was obtained by solvothermal reaction at 443?K for 72?h from a mixture of MoO3, HF, 1,4-diamino-butane (dab), water and ethyl-ene glycol. The structure consists of [Mo2O4F6](4-) anionic dimers containing strongly distorted MoO3F3 octa-hedra (with twofold symmetry), diprotonated dab cations and water mol-ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N-H?O, N-H?F and O-H?F inter-actions.

SUBMITTER: Lhoste J

PROVIDER: S-EPMC3588766 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate.

Lhoste J J Hemon-Ribaud A A Maisonneuve V V Jobic S S Bujoli-Doeuff M M

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

The title compound, (C4H14N2)2[Mo2O4F6]·H2O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO3, HF, 1,4-diamino-butane (dab), water and ethyl-ene glycol. The structure consists of [Mo2O4F6](4-) anionic dimers containing strongly distorted MoO3F3 octa-hedra (with twofold symmetry), diprotonated dab cations and water mol-ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N-H⋯O, N-H⋯F and O-H⋯F inter-actions. ...[more]

PMID: 23468731

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