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Tetra-pyridinium ?-oxido-di-?-sulfato-bis-[chloridodioxidomolybdate(VI)].

ABSTRACT: The title salt, (C(5)H(6)N)(4)[Mo(2)Cl(2)O(5)(SO(4))(2)], comprises four pyridinium cations for each [(MoClO(2))(2)(?-O)(?-SO(4))(2)](4-) anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetra-anionic bimetallic molybdenum(VI) cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non-polymeric compound with terminal oxide, sulfate and halide ligands bonded to the same metal. The hydrogen bonds connecting the pyridinium cations to the molybdenum clusters are diverse, varying from strong and directional interactions to bifurcated bonds with a subsequent loss of directionality.

SUBMITTER: Fernandes JA

PROVIDER: S-EPMC3007277 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Tetra-pyridinium μ-oxido-di-μ-sulfato-bis-[chloridodioxidomolybdate(VI)].

Fernandes José A JA Gomes Ana C AC Figueiredo Sónia S Gago Sandra S Lopes André D AD Pillinger Martyn M Ribeiro-Claro Paulo J A PJ Gonçalves Isabel S IS Almeida Paz Filipe A FA

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

The title salt, (C(5)H(6)N)(4)[Mo(2)Cl(2)O(5)(SO(4))(2)], comprises four pyridinium cations for each [(MoClO(2))(2)(μ-O)(μ-SO(4))(2)](4-) anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetra-anionic bimetallic molybdenum(VI) cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non-polymeric compound with terminal oxide, sulfate and halide ligands bonded to the same metal. The hydro ...[more]

PMID: 21588086

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