Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tetra-phenyl-phospho-nium [μ3-(4-methyl-phen-yl)tellurolato]tris-[tetra-carbonyl-iron(0)].

ABSTRACT: In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl-phenyl group and the Fe(0) atoms in a distorted tetra-hedral geometry. The average Te-Fe bond length is 2.574 (4) Å.

SUBMITTER: Li YL

PROVIDER: S-EPMC3684888 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tetra-phenyl-phospho-nium [μ3-(4-methyl-phen-yl)tellurolato]tris-[tetra-carbonyl-iron(0)].

Li Yu-Long YL Xie Bin B Zou Li-Ke LK

Acta crystallographica. Section E, Structure reports online 20130518 Pt 6

In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl-phenyl group and the Fe(0) atoms in a distorted tetra-hedral geometry. The average Te-Fe bond length is 2.574 (4) Å. ...[more]

PMID: 23794990

Similar Datasets

Tetra-phenyl-phospho-nium hydrogen oxalate.

Project description:In the title compound, C(24)H(20)P(+)·C(2)HO(4) (-), two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxyl-ate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°.

| S-EPMC2915301 | biostudies-literature

[1,4-Phenyl-enebis(methyl-ene)]bis-(tri-phenyl-phospho-nium) bis-(tetra-fluoro-borate).

Project description:The crystal structure of the title salt, C(44)H(38)P(2) (2+)2BF(4) (-), consists of discrete dications inter-laced with the BF(4) (-) counter-ions. In each cation, both phospho-nium groups lie on the same side of the plane of the central benzene ring. The tetra-fluoro-borate anions are involved in intensive thermal motion, thus some B-F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values.

| S-EPMC3239032 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50?(9), 75.51?(10) and 80.63?(10)° with each other, while in the other ligand these angles are 51.92?(10), 78.56?(11) and 86.80?(10)°. C-H?O and C-H?F inter-actions link the mol-ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944?(3):0.056?(3), 0.702?(4):0.298?(4), 0.829?(4):0.171?(4), 0.567?(4):0.433?(4), 0.545?(4):0.455?(4) and 0.920?(4):0.080?(4).

| S-EPMC3238589 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-sulfido-tungstate(VI).

Project description:The crystal structure of the title compound, (C(24)H(20)P)(2)[WS(4)], which was prepared under hydro-thermal conditions, contains tetra-phenyl-phospho-nium cations linked by supra-molecular inter-actions into chains running along the [110] and [10] directions. The [WS(4)](2-)anions, which lie on twofold axes, are located in the cavities created between the cation chains.

| S-EPMC2960978 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).

Project description:The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral [CoCl4](2-) anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.

| S-EPMC4051096 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(4-fluoro-phen-yl)phosphane-κP]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho-rus atom make dihedral angles of 80.32 (5), 52.91 (5) and 83.80 (5)° with each other. In the crystal, C-H⋯O and C-H⋯F inter-molecular inter-actions form an infinite three-dimensional network.

| S-EPMC3200925 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-iodidomanganate(II) acetone monosolvate.

Project description:The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra-phenyl-phospho-nium iodide in acetone shows a tetra-hedral complex anion [Mn-I = 2.6868?(5)-2.7281?(4)?Å and I-Mn-I = 104.011?(13)-116.164?(15)°], two tetra-phenyl-phospho-nium cations and one mol-ecule of acetone.

| S-EPMC2983621 | biostudies-literature

Acetonyltri-phenyl-phospho-nium 2,3,5-tri-phenyl-tetra-zolium tetra-chlorido-cuprate(II).

Project description:The title compound, (C21H20OP)(C19H15N4)[CuCl4], was obtained by reacting CuCl2·2H2O with a mixture of one equivalent of acetonyltri-phenyl-phospho-nium chloride and one equivalent of 2,3,5-tri-phenyl-tetra-zolium chloride in aceto-nitrile. In the structure, the Cu centre in the dianion is bonded to four chloride ligands and adopts a distorted tetra-hedral geometry. The phospho-nium cation likewise adopts the expected tetra-hedral geometry. The tetra-zolium ring forms dihedral angles of 77.68 (10), 26.85 (11) and 66.48 (10)° with the planes of the benzene rings of the substituent groups. In the crystal, weak C-H⋯Cl hydrogen-bonding inter-actions involving both cations and the anion give rise to a three-dimensional supra-molecular structure.

| S-EPMC5778489 | biostudies-literature

1,1,1-Tris(di-methyl-amino)-2-[tris-(di-methyl-amino)-phospho-ranyl-idene]diphosphinium tetra-phenyl-borate tetra-hydro-furan monosolvate.

Project description:In the tetra-hydro-furan solvate of the title salt, C12H36N6P3 (+)·C24H20B(-)·C4H8O, the cation features short P-P bond lengths [2.1111?(11) and 2.1364?(10)?Å] and a distinctly bent P-P-P angle [104.67?(4)°] that confirm that the mol-ecule is not allene-like. In the crystal, the solvent mol-ecule is linked to the cation via a weak C-H?O hydrogen bond.

| S-EPMC4051105 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tris-[N-(methyl-sulfon-yl)dithio-carbimato(2-)-?S,S']stannate(IV).

Project description:In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal occupancy. In the crystal structure, weak inter-molecular C-H?O and C-H?S inter-actions contribute to the packing stabilization.

| S-EPMC2970435 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data