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Crystal structures of di-aquadi-μ-hydroxido-tris-[tri-methyl-tin(IV)] diformatotri-methyl-stannate(IV) and di-μ-hydroxido-tris-[tri-methyl-tin(IV)] chloride monohydrate.

ABSTRACT: The title compounds, [Sn3(CH3)9(OH)2(H2O)2][Sn(CH3)3(CHO2)2] (1) and [Sn3(CH3)9(OH)2]Cl·H2O (2), are partially condensed products of hydrolysed tri-methyl-tin chloride. In the structures of 1 and 2, short cationic tris-tannatoxanes (C9H29O2Sn3) are bridged by a diformatotri-methyl-tin anion or a chloride anion, respectively. Hydrogen bridges are present and supposedly stabilize these structures against further polymerization to the known polymeric tri-methyl-tin hydroxide. Especially noteworthy is that the formate present in this structure was formed from atmospheric CO2.

SUBMITTER: Otte F 

PROVIDER: S-EPMC5050785 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

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Crystal structures of di-aquadi-μ-hydroxido-tris-[tri-methyl-tin(IV)] diformatotri-methyl-stannate(IV) and di-μ-hydroxido-tris-[tri-methyl-tin(IV)] chloride monohydrate.

Otte Felix F   Koller Stephan G SG   Golz Christopher C   Strohmann Carsten C  

Acta crystallographica. Section E, Crystallographic communications 20160930 Pt 10

The title compounds, [Sn<sub>3</sub>(CH<sub>3</sub>)<sub>9</sub>(OH)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>][Sn(CH<sub>3</sub>)<sub>3</sub>(CHO<sub>2</sub>)<sub>2</sub>] (<b>1</b>) and [Sn<sub>3</sub>(CH<sub>3</sub>)<sub>9</sub>(OH)<sub>2</sub>]Cl·H<sub>2</sub>O (<b>2</b>), are partially condensed products of hydrolysed tri-methyl-tin chloride. In the structures of <b>1</b> and <b>2</b>, short cationic tris-tannatoxanes (C<sub>9</sub>H<sub>29</sub>O<sub>2</sub>Sn<sub>3</sub>) are bridged by a d  ...[more]

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