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ABSTRACT:
SUBMITTER: Bertke JA
PROVIDER: S-EPMC3344409 | biostudies-literature | 2012 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120428 Pt 5
The asymmetric unit of the title compound, [Nd(2)(C(6)H(5)COO)(5)Cl(C(4)H(8)O(2))]·2.5C(4)H(8)O(2), consists of two Nd(III) ions bridged by one Cl(-) ion, five benzoate ions and one coordinating 1,4-dioxane mol-ecule. One Nd(III) ion is nine-coordinate, with a very distorted monocapped square-anti-prismatic geometry. It is coordinated by two chelating carboxyl-ate groups, three monodentate carboxyl-ate groups, one chloride ion and one dioxane mol-ecule. A second independent Nd(III) ion is eight- ...[more]