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Di-chlorido-{8-[2-(di-methyl-amino)-ethyl-amino]-quinoline-?(3) N,N',N''}zinc.

ABSTRACT: In the title complex, [ZnCl2(C13H17N3)], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N',N''-tridentate 8-[2-(di-methyl-amino)-ethyl-amino]-quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N-Zn-N angle of 133.25?(11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, mol-ecules are linked by N-H?Cl inter-actions. This leads to the formation of chains of mol-ecules parallel to the b-axis direction.

SUBMITTER: Al-Sudani AR

PROVIDER: S-EPMC3914037 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Di-chlorido-{8-[2-(di-methyl-amino)-ethyl-amino]-quinoline-κ(3) N,N',N''}zinc.

Al-Sudani Abdul-Razak H AR

Acta crystallographica. Section E, Structure reports online 20131204 Pt 1

In the title complex, [ZnCl2(C13H17N3)], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N',N''-tridentate 8-[2-(di-methyl-amino)-ethyl-amino]-quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N-Zn-N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cati ...[more]

PMID: 24526942

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