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Bis(4-amino-benzene-sulfonamide-?N (4))di-chlorido-zinc.

ABSTRACT: In the title compound, [ZnCl2(C6H8N2O2S)2], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra-hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn-Cl = 2.2288?(16)?Å and Zn-N = 2.060?(5)?Å]. The dihedral angle between the benzene rings is 67.1?(3)°. The crystal packing can be describe as layers in a zigzag arrangement parallel to (001). The amine H atoms act as donor atoms and participate in inter-molecular N-H?O and N-H?Cl hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Benmebarek S

PROVIDER: S-EPMC3914061 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Bis(4-amino-benzene-sulfonamide-κN (4))di-chlorido-zinc.

Benmebarek Sabrina S Boudraa Mhamed M Bouacida Sofiane S Merazig Hocine H Dénès George G

Acta crystallographica. Section E, Structure reports online 20131224 Pt 1

In the title compound, [ZnCl2(C6H8N2O2S)2], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra-hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn-Cl = 2.2288 (16) Å and Zn-N = 2.060 (5) Å]. The dihedral angle between the benzene rings is 67.1 (3)°. The crystal packing can be describe as layers in a zigzag arrangement parallel to (001). The amine H atoms act as donor atoms and partici ...[more]

PMID: 24526954

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