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Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

ABSTRACT: The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into sheets perpendicular to the a axis. C-H⋯Cl inter-actions also occur.

SUBMITTER: Govindaraj J 

PROVIDER: S-EPMC4384566 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

Govindaraj J J   Thirumurugan S S   Reddy D Snehalatha DS   Anbalagan K K   SubbiahPandi A A  

Acta crystallographica. Section E, Crystallographic communications 20150114 Pt 2

The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the  ...[more]

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