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[N,N'-Bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine-?(2) N,N']di-bromido-nickel(II).

ABSTRACT: The complex molecule in the title compound, [NiBr2(C36H40N2)], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N'-bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine ligand in a distorted tetra-hedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1?(1)°.

SUBMITTER: Yuan J 

PROVIDER: S-EPMC3998469 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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[N,N'-Bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine-κ(2) N,N']di-bromido-nickel(II).

Yuan Jianchao J   Xia Jingjing J   Xu Weibing W   Mu Yanqiong Y  

Acta crystallographica. Section E, Structure reports online 20140215 Pt 3

The complex molecule in the title compound, [NiBr2(C36H40N2)], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N'-bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine ligand in a distorted tetra-hedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1 (1)°. ...[more]

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