Ontology highlight
ABSTRACT:
SUBMITTER: Yang FL
PROVIDER: S-EPMC4011295 | biostudies-literature | 2014 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20140405 Pt 5
The asymmetric unit of the title compound, {[Mn3{W(CN)8}2(C16H16N2)3(C3H7NO)3(CH3OH)3]·2H2O} n , consists of three [Mn(N,N-di-methyl-formamide)(methanol)(3,4,7,8-tetra-methyl-1,10-phenanthroline)](2+) cations, two [W(CN)8](3-) anions and two water mol-ecules. Each water mol-ecule is disordered over three sets of sites, with a refined occupancy ratio of 0.310 (9):0.275 (9):0.415 (9) for one mol-ecule and 0.335 (9):0.288 (9):0.377 (9) for the other mol-ecule. The Mn(II) atoms exhibit a distorted o ...[more]