Unknown

Dataset Information

0

Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates.

ABSTRACT: Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral Palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple readily available starting materials.

SUBMITTER: Ardolino MJ 

PROVIDER: S-EPMC4019443 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates.

Ardolino Michael J MJ   Eno Meredith S MS   Morken James P JP  

Advanced synthesis & catalysis 20131101 17

Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral Palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple readily available starting materials. ...[more]

Similar Datasets

Unknown Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.
| S-EPMC3374959 | biostudies-literature
Unknown 1,5-Dibenzyl-3-propargyl-1,5-benzo-diazepine-2,4-dione.
| S-EPMC2971782 | biostudies-literature
Unknown HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols.
| S-EPMC4676292 | biostudies-other
Unknown 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.
| S-EPMC3006968 | biostudies-literature
Unknown Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes.
| S-EPMC6899605 | biostudies-literature
Unknown Gold-catalyzed enantioselective ring-expanding cycloisomerization of cyclopropylidene bearing 1,5-enynes.
| S-EPMC3998771 | biostudies-literature
Unknown A bidirectional S(E)' strategy for 1,5-syn and 1,5-anti stereocontrol toward the synthesis of complex polyols.
| S-EPMC3565749 | biostudies-literature
Unknown Controlling, Understanding, and Redirecting the Thermal Rearrangement of 3,3-Dicyano-1,5-enynes.
| S-EPMC6679653 | biostudies-literature
Unknown Gold(i)-catalyzed addition of aldehydes to cyclopropylidene bearing 6-aryl-1,5-enynes.
| S-EPMC5134929 | biostudies-literature
Unknown Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetates.
| S-EPMC3443958 | biostudies-literature