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[(Z)-O-Ethyl-N-propyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S-Au-P = 176.66?(5)°] due to an intra-molecular Au?O contact [2.991?(5)?Å]. Supra-molecular dimers are formed in the crystal structure mediated by C-H?N inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971786 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-O-Ethyl-N-propyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S-Au-P = 176.66 (5)°] due to an intra-molecular Au⋯O contact [2.991 (5) Å]. Supra-molecular dimers are formed in the crystal structure mediated by C-H⋯N inter-actions. ...[more]

PMID: 21578605

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