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Catena-Poly[[[bis-(1H-imidazole-?N (3))zinc(II)]-?2-imidazol-1-ido-?(2) N:N'] nitrate].

ABSTRACT: The title compound, {[Zn(C3H3N2)(C3H4N2)2]NO3} n , is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetra-hedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94?(17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06?(17)°. In the crystal, the chains are linked via bifurcated N-H?(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C-H?O hydrogen bonds and a C-H?? inter-action, forming a three-dimensional structure.

SUBMITTER: Govindhan E

PROVIDER: S-EPMC4158546 | biostudies-literature | 2014 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[[bis-(1H-imidazole-κN (3))zinc(II)]-μ2-imidazol-1-ido-κ(2) N:N'] nitrate].

Govindhan Elumalai E Ganeshraja A S AS Bhavana B B Anbalagan Krishnamoorthy K SubbiahPandi Arunachalam A

Acta crystallographica. Section E, Structure reports online 20140711 Pt 8

The title compound, {[Zn(C3H3N2)(C3H4N2)2]NO3} n , is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetra-hedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N-H⋯(O,O) hydrogen bonds, fo ...[more]

PMID: 25249881

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