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Crystal structure of di-chlorido-bis-[2-(phenyl-diazen-yl)pyridine-?N (1)]zinc.

ABSTRACT: The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-H?Cl inter-actions [C?Cl = 3.411?(2) and 3.675?(2)?Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

SUBMITTER: Vittaya L 

PROVIDER: S-EPMC4645076 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of di-chlorido-bis-[2-(phenyl-diazen-yl)pyridine-κN (1)]zinc.

Vittaya Luksamee L   Leesakul Nararak N   Saithong Saowanit S   Chainok Kittipong K  

Acta crystallographica. Section E, Crystallographic communications 20151024 Pt 11

The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers p  ...[more]

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