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Aminosilanes derived from 1H-benzimidazole-2(3H)-thione.

ABSTRACT: Two new molecular structures, namely 1,3-bis(trimethylsilyl)-1H-benzimidazole-2(3H)-thione, C13H22N2SSi2, (2), and 1-trimethylsilyl-1H-benzimidazole-2(3H)-thione, C10H14N2SSi, (3), are reported. Both systems were derived from 1H-benzimidazole-2(3H)-thione. Noncovalent C-H···? interactions between the centroid of the benzmidazole system and the SiMe3 groups form helicoidal arrangements in (2). Dimerization of (3) results in the formation of R2(2)(8) rings via N-H···S interactions, along with parallel ?-? interactions between imidazole and benzene rings.

SUBMITTER: Palomo-Molina J 

PROVIDER: S-EPMC4554437 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Aminosilanes derived from 1H-benzimidazole-2(3H)-thione.

Palomo-Molina Juliana J   García-Báez Efrén V EV   Contreras Rosalinda R   Pineda-Urbina Kayim K   Ramos-Organillo Angel A  

Acta crystallographica. Section C, Structural chemistry 20150812 Pt 9

Two new molecular structures, namely 1,3-bis(trimethylsilyl)-1H-benzimidazole-2(3H)-thione, C13H22N2SSi2, (2), and 1-trimethylsilyl-1H-benzimidazole-2(3H)-thione, C10H14N2SSi, (3), are reported. Both systems were derived from 1H-benzimidazole-2(3H)-thione. Noncovalent C-H···π interactions between the centroid of the benzmidazole system and the SiMe3 groups form helicoidal arrangements in (2). Dimerization of (3) results in the formation of R2(2)(8) rings via N-H···S interactions, along with para  ...[more]

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