Ontology highlight
ABSTRACT:
SUBMITTER: Corfield PW
PROVIDER: S-EPMC4647444 | biostudies-literature | 2015 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150917 Pt 10
The title compound, [Au(C18H10F4PS)Cl2], crystallizes as neutral mol-ecules, with the Au(III) atom coordinated by two Cl atoms and by the P and S atoms of the bidentate phosphanyl thiol-ate ligand, in a slightly distorted square-planar environment. The mol-ecules are linked into centrosymmetric dimers via long axial Au-Cl bonds of 3.393 (4) Å. This axial Au-Cl distance is longer than is usually seen, although one other example has been given. Dimer formation may explain the unexpectedly low solu ...[more]