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Crystal structure of tris-(trans-1,2-di-amino-cyclo-hexane-?(2) N,N')cobalt(III) trichloride monohydrate.

ABSTRACT: The synthesis of the title hydrated complex salt, [Co(C6H14N2)3]Cl3·H2O, from racemic trans-1,2-di-amino-cyclo-hexane and [CoCl(NH3)5]Cl2 and its structural characterization are presented in this paper. The product was synthesized in the inter-est of understanding the hydrogen-bonding patterns of coordination complexes. Previous characterizations of the product in the I-42d space group have not yielded coordinates; thus, this paper provides the first coordinates for this complex in this space group. The octahedrally coordinated cation adopts twofold rotation symmetry, with outer-sphere chloride counter-ions and solvent water mol-ecules forming a hydrogen-bonded network with amine H atoms.

SUBMITTER: Gallagher MK 

PROVIDER: S-EPMC4704754 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of tris-(trans-1,2-di-amino-cyclo-hexane-κ(2) N,N')cobalt(III) trichloride monohydrate.

Gallagher Megan K MK   Oliver Allen G AG   Lappin A Graham AG  

Acta crystallographica. Section E, Crystallographic communications 20160101 Pt 1

The synthesis of the title hydrated complex salt, [Co(C6H14N2)3]Cl3·H2O, from racemic trans-1,2-di-amino-cyclo-hexane and [CoCl(NH3)5]Cl2 and its structural characterization are presented in this paper. The product was synthesized in the inter-est of understanding the hydrogen-bonding patterns of coordination complexes. Previous characterizations of the product in the I-42d space group have not yielded coordinates; thus, this paper provides the first coordinates for this complex in this space gr  ...[more]

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