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Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization.


ABSTRACT: The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)-catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.

SUBMITTER: Carreras J 

PROVIDER: S-EPMC5053274 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization.

Carreras Javier J   Kirillova Mariia S MS   Echavarren Antonio M AM  

Angewandte Chemie (International ed. in English) 20160427 25


The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)-catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone. ...[more]

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