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Crystal structure of fac-[2-(4-methyl-5-phenyl-pyridin-2-yl)phenyl-?2C1,N]bis-[2-(pyridin-2-yl)phenyl-?2C1,N]iridium(III).

ABSTRACT: In the title compound, [Ir(C11H8N)2(C18H14N)], the IrIII ion adopts a distorted octa-hedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methyl-pyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIII ion lies almost in the equatorial plane [deviation = 0.0069?(15)?Å]. In the crystal, inter-molecular ?-? stacking inter-actions, as well as inter-molecular C-H?? inter-actions, are present, leading to a three-dimensional network.

SUBMITTER: Lee CH

PROVIDER: S-EPMC5137604 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of fac-[2-(4-methyl-5-phenyl-pyridin-2-yl)phenyl-κ2C1,N]bis-[2-(pyridin-2-yl)phenyl-κ2C1,N]iridium(III).

Lee Chi-Heon CH Moon Suk-Hee SH Park Ki-Min KM Kang Youngjin Y

Acta crystallographica. Section E, Crystallographic communications 20161108 Pt 12

In the title compound, [Ir(C11H8N)2(C18H14N)], the IrIII ion adopts a distorted octa-hedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methyl-pyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIII ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, inter-molecular ...[more]

PMID: 27980826

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