Unknown

Dataset Information

0

Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration.


ABSTRACT: A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

SUBMITTER: Callingham M 

PROVIDER: S-EPMC5765452 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration.

Callingham Michael M   Partridge Benjamin M BM   Lewis William W   Lam Hon Wai HW  

Angewandte Chemie (International ed. in English) 20171124 51


A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration. ...[more]

Similar Datasets

| S-EPMC5488243 | biostudies-literature
| S-EPMC10439940 | biostudies-literature
| S-EPMC6857534 | biostudies-literature
| S-EPMC8179376 | biostudies-literature
| S-EPMC8157494 | biostudies-literature
| S-EPMC2925184 | biostudies-literature
| S-EPMC4557058 | biostudies-literature
| S-EPMC4464529 | biostudies-literature
| S-EPMC3663875 | biostudies-literature
| S-EPMC3069138 | biostudies-literature