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Crystal structure of bromido-penta-kis-(tetra-hydro-furan-?O)magnesium bis-[1,2-bis-(di-phenyl-phosphan-yl)benzene-?2 P,P']cobaltate(-1) tetra-hydro-furan disolvate.

ABSTRACT: Structural characterization of the ionic title complex, [MgBr(THF)5][Co(dpbz)2]·2THF [THF is tetra-hydro-furan, C4H8O; dpbz is 1,2-bis-(di-phenyl-phosphan-yl)benzene, C30H24P2], revealed a well-separated cation and anion co-crystallized with two THF solvent mol-ecules that inter-act with the cation via weak C-H?O contacts. The geometry about the cobalt center is pseudo-tetra-hedral, as is expected for a d 10 metal center, only deviating from an ideal tetra-hedral geometry because of the restrictive bite angles of the bidentate phosphane ligands. Three THF ligands of the cation and one co-crystallized THF solvent mol-ecule are each disordered over two orientations. In the extended structure, the cations and THF solvent mol-ecules are arranged in (100) sheets that alternate with layers of anions, the latter of which show various ?-inter-actions, which may explain the particular packing arrangement.

SUBMITTER: Girigiri PB 

PROVIDER: S-EPMC6362642 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of bromido-penta-kis-(tetra-hydro-furan-κ<i>O</i>)magnesium bis-[1,2-bis-(di-phenyl-phosphan-yl)benzene-κ<sup>2</sup> <i>P</i>,<i>P</i>']cobaltate(-1) tetra-hydro-furan disolvate.

Girigiri Patience B PB   Carpenter Stephanie H SH   Brennessel William W WW   Neidig Michael L ML  

Acta crystallographica. Section E, Crystallographic communications 20190131 Pt 2

Structural characterization of the ionic title complex, [MgBr(THF)<sub>5</sub>][Co(dpbz)<sub>2</sub>]·2THF [THF is tetra-hydro-furan, C<sub>4</sub>H<sub>8</sub>O; dpbz is 1,2-bis-(di-phenyl-phosphan-yl)benzene, C<sub>30</sub>H<sub>24</sub>P<sub>2</sub>], revealed a well-separated cation and anion co-crystallized with two THF solvent mol-ecules that inter-act with the cation <i>via</i> weak C-H⋯O contacts. The geometry about the cobalt center is pseudo-tetra-hedral, as is expected for a <i>d</i>  ...[more]

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