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{?-1,2-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]-1,2-diethyl-hydrazine-?P:P'}bis-[chloridogold(I)] tetra-hydro-furan disolvate.

ABSTRACT: The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98?(3)°]. The nuclei are 3.1414?(2)?Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H?Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further attached to the stacks through weak C-H?O hydrogen bonding from the THF O atom to two separate H atoms on the complex.

SUBMITTER: Kriel FH 

PROVIDER: S-EPMC3201433 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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{μ-1,2-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]-1,2-diethyl-hydrazine-κP:P'}bis-[chloridogold(I)] tetra-hydro-furan disolvate.

Kriel Frederik H FH   Fernandes Manuel A MA   Coates Judy J  

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H⋯Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further attached to the stacks through weak C-H⋯O hydrogen bonding from the THF O atom to two separate H atoms on t  ...[more]

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