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Crystal structure of (N,N'-ethyl-enebis{3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]-4-oxo-pentan-2-iminato})copper(II)-3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]pentane-2,4-dione (1/1).

ABSTRACT: In the title 1:1 co-crystal, [Cu(C₂₄H₂₄N₈O₆)]·C₁₁H₁₁N₃O₄, each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol-ecules of the Cu^II complex are connected via C-H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra-molecular networks. Mol-ecules of the aryl-hydrazone component are linked by C-H⋯O inter-actions into zigzag strands showing no inter-strand association.

SUBMITTER: Marten J

PROVIDER: S-EPMC6658969 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of (N,N'-ethyl-enebis{3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]-4-oxo-pentan-2-iminato})copper(II)-3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]pentane-2,4-dione (1/1).

Marten Jan J Seichter Wilhelm W Weber Edwin E

Acta crystallographica. Section E, Crystallographic communications 20190521 Pt 6

In the title 1:1 co-crystal, [Cu(C24H24N8O6)]·C11H11N3O4, each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol-ecules of the CuII complex are connected via C-H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra-molecular networks. Mol-ecules of the aryl-hydrazone component are linked by C-H⋯O inter-a ...[more]

PMID: 31391977

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