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Crystal structure and photoluminescence properties of catena-poly[[bis-(1-benzyl-1H-imidazole-?N 3)cadmium(II)]-di-?-azido-?4 N 1:N 3].

ABSTRACT: The new title one-dimensional CdII coordination polymer, [Cd(C10H10N2)2(?1,3-N3)2] n , has been synthesized and structurally characterized by single-crystal X-ray diffraction. The asymmetric unit consists of a CdII ion, one azide and one 1-benzyl-imidazole (bzi) ligand. The CdII ion is located on an inversion centre and is surrounded in a distorted octa-hedral coordination sphere by six N atoms from four symmetry-related azide ligands and two symmetry-related bzi ligands. The CdII ions are linked by double azide bridging ligands within a ?1,3-N3 end-to-end (EE) coordination mode, leading to a one-dimensional linear structure extending parallel to [100]. The supra-molecular framework is stabilized by the presence of weak C-H?N inter-actions, ?-? stacking [centroid-to-centroid distance of 3.832?(2)?Å] and C-H?? inter-actions between neighbouring chains.

SUBMITTER: Assavajamroon P 

PROVIDER: S-EPMC6829744 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Crystal structure and photoluminescence properties of <i>catena</i>-poly[[bis-(1-benzyl-1<i>H</i>-imidazole-κ<i>N</i> <sup>3</sup>)cadmium(II)]-di-μ-azido-κ<sup>4</sup> <i>N</i> <sup>1</sup>:<i>N</i> <sup>3</sup>].

Assavajamroon Ploy P   Kielar Filip F   Chainok Kittipong K   Wannarit Nanthawat N  

Acta crystallographica. Section E, Crystallographic communications 20191029 Pt 11

The new title one-dimensional Cd<sup>II</sup> coordination polymer, [Cd(C<sub>10</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>(μ<sub>1,3</sub>-N<sub>3</sub>)<sub>2</sub>] <sub><i>n</i></sub> , has been synthesized and structurally characterized by single-crystal X-ray diffraction. The asymmetric unit consists of a Cd<sup>II</sup> ion, one azide and one 1-benzyl-imidazole (bzi) ligand. The Cd<sup>II</sup> ion is located on an inversion centre and is surrounded in a distorted octa-hedral coordinat  ...[more]

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