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Crystal structure and photoluminescent properties of bis-(4'-chloro-2,2':6',2''-terpyrid-yl)cobalt(II) dichloride tetra-hydrate.

ABSTRACT: In the title hydrated complex, [Co(C15H10ClN3)2]Cl2·4H2O, the complete dication is generated by symmetry. The CoN6 moiety shows distortion from regular octa-hedral geometry with the trans bond angles of two N-Co-N units being 160.62?(9)°. In the crystal, O-H?Cl and C-H?O inter-actions link the components into (001) sheets. The title compound exhibits blue-light emission, as indicated by photoluminescence data, and a HOMO-LUMO energy separation of 2.23?eV was obtained from its diffuse reflectance spectrum.

SUBMITTER: Thippeswamy B

PROVIDER: S-EPMC7133030 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Crystal structure and photoluminescent properties of bis-(4'-chloro-2,2':6',2''-terpyrid-yl)cobalt(II) dichloride tetra-hydrate.

Thippeswamy B B Suchetan P A PA Mahadevan K M KM Nagabhushana H H Vijayakumar G R GR

Acta crystallographica. Section E, Crystallographic communications 20200305 Pt 4

In the title hydrated complex, [Co(C15H10ClN3)2]Cl2·4H2O, the complete dication is generated by symmetry. The CoN6 moiety shows distortion from regular octa-hedral geometry with the trans bond angles of two N-Co-N units being 160.62 (9)°. In the crystal, O-H⋯Cl and C-H⋯O inter-actions link the components into (001) sheets. The title compound exhibits blue-light emission, as indicated by photoluminescence data, an ...[more]

PMID: 32280491

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