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Dehydrogenative C-H Phenochalcogenazination.

ABSTRACT: Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C-H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C-N bond-forming processes operate under simple reaction conditions with highly sustainable O₂ serving as the terminal oxidant.

SUBMITTER: Cremer C

PROVIDER: S-EPMC8155573 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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Dehydrogenative C-H Phenochalcogenazination.

Cremer Christopher C Eltester M Alexander MA Bourakhouadar Hicham H Atodiresei Iuliana L IL Patureau Frederic W FW

Organic letters 20210413 9

Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C-H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C-N bond-forming processes operate under simple reaction conditions with highly sustainable O<sub>2</sub> serving as the terminal oxidant. ...[more]

PMID: 33848168

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