Ontology highlight
ABSTRACT:
SUBMITTER: Urkalan KB
PROVIDER: S-EPMC2794962 | biostudies-other | 2009 Dec
REPOSITORIES: biostudies-other
Journal of the American Chemical Society 20091201 50
An unconventional route for the formation of sp(3)-sp(3) C-C bonds from various styrenes and an organozinc reagent in a formal alkene hydroalkylation process is detailed. Mechanistically, this process is proposed to proceed by initial transmetalation followed by formation of a Pd-H species, which is subsequently trapped by the styrene. ...[more]