Dataset Information
Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-carbon sp3-sp3 bonds under oxidative conditions.
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ABSTRACT:
SUBMITTER: Urkalan KB
PROVIDER: S-EPMC2794962 | biostudies-other | 2009 Dec
REPOSITORIES: biostudies-other
Publications
Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-carbon sp3-sp3 bonds under oxidative conditions.
Journal of the American Chemical Society 20091201 50
An unconventional route for the formation of sp(3)-sp(3) C-C bonds from various styrenes and an organozinc reagent in a formal alkene hydroalkylation process is detailed. Mechanistically, this process is proposed to proceed by initial transmetalation followed by formation of a Pd-H species, which is subsequently trapped by the styrene. ...[more]