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Bis(4-ferrocenylbenzoato-?O)tetra-kis(methanol-?O)cadmium(II).

ABSTRACT: The complete mol-ecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol mol-ecules and by the O atoms of the two carboxyl-ate anions (the latter in cis geometry), resulting in a distorted CdO(6) octa-hedron. The phenyl-ene ring is almost coplanar with its adjacent cyclo-penta-dienyl ring [dihedral angle = 8.2?(2)°]. The uncoordin-ated carboxyl-ate O atom acts as acceptor to two O-H?O hydrogen bonds from the methanol mol-ecules, giving rise to a layered network.

SUBMITTER: Zhao HY

PROVIDER: S-EPMC2959802 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis(4-ferrocenylbenzoato-κO)tetra-kis(methanol-κO)cadmium(II).

Zhao Hong-Ying HY Song Lian-Qing LQ Wang Jing-Wu JW Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20081126 Pt 12

The complete mol-ecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol mol-ecules and by the O atoms of the two carboxyl-ate anions (the latter in cis geometry), resulting in a distorted CdO(6) octa-hedron. The phenyl-ene ring is almost coplanar with its adjacent cyclo-penta-dienyl ring [dihedral angle = 8.2 (2) ...[more]

PMID: 21581214

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