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(2,2'-Bipyridine)bis-(triphenyl-phosphine)copper(I) nitrate chloro-form solvate hemihydrate.

ABSTRACT: In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra-hedrally coordinated by a bidentate 2,2'-bipyridine ligand and two PPh(3) ligands. The Cu-N and Cu-P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra-hedral geometry. The bipyridine ligand is twisted [14.2?(4)°] about the ring-ring C-C bond. The nitrate anion and the water and chloro-form mol-ecules of solvation are disordered. In the crystal structure, there are O(water)-H?O(nitrate), C-H?O(water) and C-H?O(nitrate) hydrogen bonds.

SUBMITTER: Navarro M 

PROVIDER: S-EPMC2960891 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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(2,2'-Bipyridine)bis-(triphenyl-phosphine)copper(I) nitrate chloro-form solvate hemihydrate.

Navarro Maribel M   Corona Oscar A OA   González Teresa T   Capparelli Mario V MV  

Acta crystallographica. Section E, Structure reports online 20080312 Pt 4

In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra-hedrally coordinated by a bidentate 2,2'-bipyridine ligand and two PPh(3) ligands. The Cu-N and Cu-P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra-hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring-ring C-C bond. The nitrate anion and the water and chloro-form mol-ecules of so  ...[more]

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