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Bis(1-ferrocenylethanone oximato)triphenyl-anti-mony(V).

ABSTRACT: In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two inter-molecular C-H?? inter-actions.

SUBMITTER: Fan J

PROVIDER: S-EPMC2967863 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis(1-ferrocenylethanone oximato)triphenyl-anti-mony(V).

Fan Jinshi J

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two inter-molecular C-H⋯π inter-actions. ...[more]

PMID: 21581484

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