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(2,9-Dimethyl-4,7-diphenyl-1,10-phen-anthroline-?N,N')bis-(thio-cyanato-?S)mercury(II).

ABSTRACT: In the mol-ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20?(3)° . In the crystal structure, ?-? contacts between phenanthroline rings [centroid-centroid distance = 3.981?(1)?Å] may stabilize the structure.

SUBMITTER: Alizadeh R

PROVIDER: S-EPMC2969232 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(2,9-Dimethyl-4,7-diphenyl-1,10-phen-anthroline-κN,N')bis-(thio-cyanato-κS)mercury(II).

Alizadeh Robabeh R

Acta crystallographica. Section E, Structure reports online 20090624 Pt 7

In the mol-ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π-π contacts between phenanthroline rings [centroid-centroid distance = 3.981 (1) Å] may stabi ...[more]

PMID: 21582740

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