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Di-?-chlorido-bis-[chlorido(N,N'-dibenzyl-propane-1,2-diamine-?N,N')copper(II)].

ABSTRACT: In the title complex, [Cu(2)Cl(4)(C(17)H(22)N(2))(2)], the Cu(II) cation is coordinated by a N,N'-dibenzyl-propane-1,2-diamine ligand and two Cl(-) anions, and a Cl(-) anion from an adjacent mol-ecule further bridges to the Cu(II) cation in the apical position, with a longer Cu-Cl distance of 2.9858?(18)?Å, forming a centrosymmetric dimeric complex in which each Cu(II) cation is in a distorted square-pyramidal geometry. Intra-molecular N-H?Cl hydrogen bonding is observed in the dimeric complex.

SUBMITTER: Liu YF

PROVIDER: S-EPMC2971131 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Di-μ-chlorido-bis-[chlorido(N,N'-dibenzyl-propane-1,2-diamine-κN,N')copper(II)].

Liu Yu-Fen YF Rong Da-Fu DF Xia Hai-Tao HT Wang Da-Qi DQ

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title complex, [Cu(2)Cl(4)(C(17)H(22)N(2))(2)], the Cu(II) cation is coordinated by a N,N'-dibenzyl-propane-1,2-diamine ligand and two Cl(-) anions, and a Cl(-) anion from an adjacent mol-ecule further bridges to the Cu(II) cation in the apical position, with a longer Cu-Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each Cu(II) cation is in a distorted square-pyramidal geometry. Intra-molecular N-H⋯Cl hydrogen bonding is observed in the dimeric complex. ...[more]

PMID: 21578213

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