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Bis(N-benzyl-N-isopropyl-dithio-carbamato-?S)di-n-butyl-tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0?(2) to 136.9?(2)°, the covalent Sn-S lengths from 2.529?(1) to 2.544?(1)?Å, and the dative Sn?S lengths from 2.831?(1) to 3.042?(1)?Å in the five independent mol-ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints.

SUBMITTER: Baba I

PROVIDER: S-EPMC2977631 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis(N-benzyl-N-isopropyl-dithio-carbamato-κS)di-n-butyl-tin(IV).

Baba Ibrahim I Akmal Nor Syaidatul NS Awang Normah N Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0 (2) to 136.9 (2)°, the covalent Sn-S lengths from 2.529 (1) to 2.544 (1) Å, and the dative Sn←S lengths from 2.831 (1) to 3.042 (1) Å in the five independent mol-ecules comprising the asymmetric unit. Two of the buty ...[more]

PMID: 21583817

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