Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(N-isopropyl-N-methyl-dithio-carbamato-?S,S')diphenyl-tin(IV).

ABSTRACT: The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis.

SUBMITTER: Muthalib AF

PROVIDER: S-EPMC2983838 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')diphenyl-tin(IV).

Muthalib Amirah Faizah AF Baba Ibrahim I Farina Yang Y Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. ...[more]

PMID: 21580469

Similar Datasets

Di-tert-butyl-bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')tin(IV).

Project description:The dithio-carbamate anions in the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. The crystal studied was a non-merohedral twin, the ratio of the twin components being 0.82 (1):0.18 (1).

| S-EPMC2983955 | biostudies-literature

(N-Benzyl-N-isopropyl-dithio-carbamato)chloridodiphenyl-tin(IV).

Project description:The Sn(IV) atom in the title organotin dithio-carbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra-molecular C-H⋯Cl and C-H⋯S contacts precludes the Cl and S atoms from forming significant inter-molecular contacts. The presence of C-H⋯π contacts leads to the formation of supra-molecular arrays that stack along the b axis.

| S-EPMC3007920 | biostudies-literature

Bis(N-ethyl-N-methyl-dithio-carbamato-?S,S')diphenyl-tin(IV).

Project description:The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(4)H(8)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis.

| S-EPMC2983830 | biostudies-other

Bis(N-benzyl-N-isopropyl-dithio-carbamato-?S)di-n-butyl-tin(IV).

Project description:The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0?(2) to 136.9?(2)°, the covalent Sn-S lengths from 2.529?(1) to 2.544?(1)?Å, and the dative Sn?S lengths from 2.831?(1) to 3.042?(1)?Å in the five independent mol-ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints.

| S-EPMC2977631 | biostudies-other

Di-n-butyl-bis(N-n-butyl-N-ethyl-dithio-carbamato-?S)tin(IV).

Project description:The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn-S = 2.521?(2) and Sn?S = 2.933?(2)?Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithio-carbamate unit are disordered about another mirror plane.

| S-EPMC2977630 | biostudies-literature

Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl-dithio-carbamato-?2S,S')triphenyl-tin(IV) and [N-methyl-N-(2-phenyl-ethyl)-dithio-carbamato-?2S,S']tri-phenyl-tin(IV).

Project description:The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamate compounds, viz. [Sn(C6H5)3(C8H16NS2)], (I), and [Sn(C6H5)3(C10H12NS2)], (II), are described. The di-thio-carbamate ligand in each mol-ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra-hedral C3S coordin-ation geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The mol-ecular packing in both compounds features C-H??(Sn-phen-yl) inter-actions. In (I), the donors are Sn-phenyl-C-H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C-H and methyl-C-H groups leading to supra-molecular chains propagating along the b axis. The identified aggregates assemble into their respective crystals with no directional inter-actions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (>99% in each case) of H?H, C?H/H?C and S?H/H?S contacts on the respective Hirshfeld surface.

| S-EPMC5947476 | biostudies-literature

Bis(N-isopropyl-N-methyl-dithio-carbamato-?S,S')(1,10-phenanthroline-?N,N')zinc.

Project description:The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H?S, C-H??(ZnS(2)C) and ?-? [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955?(13)?Å] inter-actions.

| S-EPMC3089284 | biostudies-literature

(2,2'-Bipyridine-?N,N')bis-(N-isopropyl-N-methyl-dithio-carbamato-?S,S')cadmium.

Project description:The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 2,2'-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H?S inter-actions, leading to linear supra-molecular chains along the a axis. The primary connections between these are by ?-? stacking inter-actions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455?(10)?Å]. Overall, the crystal structure may be described as comprising double layers of mol-ecules that stack along the b axis.

| S-EPMC3089361 | biostudies-literature

Di-n-butyl-bis-(N-cyclo-hexyl-N-ethyl-dithio-carbamato-?S,S')tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(9)H(16)NS(2))(2)], is chelated by the two dithio-carbamate ions in a six-coordinate skew-trapezoidal-bipyramidal geometry. The two butyl groups are disordered over two positions in a 1:1 ratio.

| S-EPMC3007498 | biostudies-literature

(N-Ethyl-N-phenyl-dithio-carbamato-?S)triphenyl-tin(IV).

Project description:The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol-ecules in the asymmetric unit and each features a tetra-hedrally coordinated Sn(IV) atom as the dithio-carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn?S(thione) = 3.1477?(6) and 2.9970?(5)?Å for the independent mol-ecules], distortions from the ideal geometry are evident [the widest angle being 120.48?(5)°]. The most notable feature of the crystal packing is the formation of C-H?? inter-actions that lead to the formation of supra-molecular layers parallel to ([Formula: see text]2[Formula: see text]).

| S-EPMC3254327 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data