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Lutetium(III) cyclo-tetra-phosphate.

ABSTRACT: Single crystals of the title compound, tetra-lutetium(III) tris-(cyclo-tetra-phosphate), Lu(4)(P(4)O(12))(3), were obtained by solid-state reaction. The cubic structure is isotypic with its Al(III) and Sc(III) analogues and is built up from four-membered (P(4)O(12))(4-) phosphate ring anions ( symmetry), isolated from each other and further linked through isolated LuO(6) octa-hedra (.3. symmetry) via corner sharing. Each LuO(6) octa-hedron is linked to six (P(4)O(12))(4-) rings, while each (P(4)O(12))(4-) ring is linked to eight LuO(6) octa-hedra.

SUBMITTER: Mbarek A

PROVIDER: S-EPMC2979408 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Lutetium(III) cyclo-tetra-phosphate.

Mbarek Aïcha A Fourati Mohieddine M Zambon Daniel D Avignant Daniel D

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

Single crystals of the title compound, tetra-lutetium(III) tris-(cyclo-tetra-phosphate), Lu(4)(P(4)O(12))(3), were obtained by solid-state reaction. The cubic structure is isotypic with its Al(III) and Sc(III) analogues and is built up from four-membered (P(4)O(12))(4-) phosphate ring anions ( symmetry), isolated from each other and further linked through isolated LuO(6) octa-hedra (.3. symmetry) via corner sharing. Each LuO(6) octa-hedron is linked to six (P(4)O(12))(4-) rings, while each (P(4) ...[more]

PMID: 21579264

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