Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{2,6-Bis[(4-bromo-phen-yl)imino-meth-yl]pyridine-?N,N',N''}trichlorido-chromium(III).

ABSTRACT: In the title compound, [CrCl(3)(C(19)H(13)Br(2)N(3))], the Cr(3+ )ion is coordinated by the tridentate 2,6-bis-[(4-bromo-phen-yl)imino-meth-yl]pyridine Schiff base ligand in a fac-octa-hedral geometry. The dihedral angles between the pyridine and benzene rings are 23.9?(6) and 70.7?(1)°.

SUBMITTER: Li XP

PROVIDER: S-EPMC2983151 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

{2,6-Bis[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N',N''}trichlorido-chromium(III).

Li Xiao-Ping XP Liu Yong-Yong YY Zhao Jian-She JS

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10

In the title compound, [CrCl(3)(C(19)H(13)Br(2)N(3))], the Cr(3+ )ion is coordinated by the tridentate 2,6-bis-[(4-bromo-phen-yl)imino-meth-yl]pyridine Schiff base ligand in a fac-octa-hedral geometry. The dihedral angles between the pyridine and benzene rings are 23.9 (6) and 70.7 (1)°. ...[more]

PMID: 21587373

Similar Datasets

(E)-4-Bromo-2-[(2,6-diisopropyl-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(19)H(22)BrNO, the dihedral angle between the benzene rings is 76.17?(14)° and an intra-molecular O-H?N hydrogen bond with an S(6) graph-set motif is present. One methyl group is disordered over two sets of sites with site occupancies of 0.66?(3) and 0.34?(3). A weak inter-molecular C-H?? inter-action is observed in the crystal structure.

| S-EPMC3379361 | biostudies-literature

2-Bromo-4-chloro-6-[(2,6-diisopropyl-phen-yl)imino-meth-yl]phenol.

Project description:There are two molecules in the asymmetric unit of the title compound, C(19)H(21)BrClNO, with dihedral angles between the aromatic rings of 70.0 (2) and 81.9 (3)°. The crystal structure is stabilized by inter-molecular C-H⋯π and C-Br⋯π inter-actions. In additional, the stacked mol-ecules exhibit intra-molecular O-H⋯N hydrogen bonds.

| S-EPMC2959941 | biostudies-literature

Dichlorido{2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc.

Project description:In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra-hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine and two chloride anions. In the crystal, adjacent mol-ecules are connected through C-H?Cl hydrogen bonds between a C-H group of the ligand and a Cl(-) anion, leading to a chain-like structure along the b direction.

| S-EPMC3297262 | biostudies-literature

2,6-Bis(bromo-meth-yl)pyridine.

Project description:In the title mol-ecule, C7H7Br2N, the C-Br vectors of the bromo-methyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the mol-ecules related by a c-glide-plane operation are arranged into stacks along the c axis, with centroid-centroid distances between neighboring aromatic rings of 3.778?(2)?Å. A short Br?Br contact of 3.6025?(11)?Å is observed within a pair of inversion-related mol-ecules.

| S-EPMC3914046 | biostudies-literature

{2-[(4-Bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}diiodidozinc(II).

Project description:In the title compound, [ZnI(2)(C(12)H(9)BrN(2))], the metal centre displays a moderately distorted tetra-hedral coordination geometry defined by two iodide anions and two N atoms of the organic ligand. The dihedral angle between the pyridine and benzene rings is 15.15 (13)°.

| S-EPMC2961941 | biostudies-literature

Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc(II).

Project description:In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04?(17)°.

| S-EPMC2977329 | biostudies-literature

4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.

Project description:In the title compound, C(14)H(11)BrN(2)O(2), the mean planes of the two benzene rings are almost parallel to each other, making a dihedral angle of 4.09?(1)°. An intra-molecular O-H?N hydrogen bond occurs. In the crystal, inter-molecular O-H?N and C-H?O hydrogen bonds link the mol-ecules into a chain-like supra-molecular structure.

| S-EPMC3007216 | biostudies-literature

2-[(3-Bromo-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(13)H(10)BrNO, was prepared by reaction of 3-bromo-aniline with 2-hydroxy-benzaldehyde at 377?K. The mol-ecular structure and packing are stabilized by an intra-molecular O-H?N hydrogen-bond inter-action.

| S-EPMC2960578 | biostudies-literature

Di-?-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-?N,N'}-chloridomercury(II)).

Project description:The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

| S-EPMC2977257 | biostudies-literature

4-(4-Bromo-phen-yl)-2,6-diphenyl-pyridine.

Project description:In the title compound, C(23)H(16)BrN, the three benzene rings show a disrotatory counter-rotating arrangement around the central pyridine ring and are twisted with respect to the pyridine ring with dihedral angles of 19.56?(13), 27.54?(13) and 30.51?(13)°.

| S-EPMC2972060 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data