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Di-?-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-?N,N'}-chloridomercury(II)).

ABSTRACT: The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

SUBMITTER: Mahmoudi A

PROVIDER: S-EPMC2977257 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II)).

Mahmoudi Ali A Dehghanpour Saeed S Khalaj Mehdi M Pakravan Shabnam S

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other. ...[more]

PMID: 21583352

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