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Bis(N-ethyl-N-methyl-dithio-carbamato-?S,S')diphenyl-tin(IV).

ABSTRACT: The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(4)H(8)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis.

SUBMITTER: Muthalib AF

PROVIDER: S-EPMC2983830 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(N-ethyl-N-methyl-dithio-carbamato-κS,S')diphenyl-tin(IV).

Muthalib Amirah Faizah AF Baba Ibrahim I Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(4)H(8)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. ...[more]

PMID: 21580470

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Project description:The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(9)H(16)NS(2))(2)], is chelated by the two dithio-carbamate ions in a six-coordinate skew-trapezoidal-bipyramidal geometry. The two butyl groups are disordered over two positions in a 1:1 ratio.

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(N-Butyl-N-phenyl-dithio-carbamato-?S)triphenyl-tin(IV).

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