Browse
Submit Data
Databases
API
Help

Dataset Information

7 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{2-[1-(benzyl-imino)-eth-yl]phenolato}palladium(II).

ABSTRACT: In the title compound, [Pd(C(15)H(14)NO)(2)], the Pd atom lies on an inversion center and is coordinated by two ligand mol-ecules through the O and N atoms in a bidentate manner, forming a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings in the ligand is 76.53?(19)°. The mol-ecular packing is stablized by C-H?O and C-H?? inter-actions.

SUBMITTER: Mohd Tajuddin A

PROVIDER: S-EPMC3007840 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis{2-[1-(benzyl-imino)-eth-yl]phenolato}palladium(II).

Mohd Tajuddin Amalina A Bahron Hadariah H Wan Ibrahim Wan Nazihah WN Yamin Bohari M BM

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the title compound, [Pd(C(15)H(14)NO)(2)], the Pd atom lies on an inversion center and is coordinated by two ligand mol-ecules through the O and N atoms in a bidentate manner, forming a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings in the ligand is 76.53 (19)°. The mol-ecular packing is stablized by C-H⋯O and C-H⋯π inter-actions. ...[more]

PMID: 21588512

Similar Datasets

Bis[2-(1-imino-eth-yl)phenolato-?N,O]nickel(II).

Project description:There are one and a half independent mol-ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol-ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter-molecular N-H?O hydrogen bonds link three mol-ecules into centrosymmetric trimer. The crystal packing exhibits weak inter-molecular C-H?O hydrogen bonds and voids of 37?Å(3).

| S-EPMC3254291 | biostudies-literature

Bis[?-2-(benzyl-imino-meth-yl)-4-chloro-phenolato]bis[chloridocopper(II)].

Project description:The title complex, [Cu(2)(C(14)H(11)ClNO)(2)Cl(2)], has a centrosymmetric dinuclear structure where two symmetry-related copper(II) metal centres are bridged by the O atoms of two phen-oxy groups. Each copper(II) centre displays a distorted tetra-hedral coordination provided by one N atom and two O atoms from two Schiff base ligands and by one Cl atom. The Cu?Cu separation is 3.0702?(9)?Å.

| S-EPMC2915143 | biostudies-literature

Crystal structure of bis-(2-{1-[(E)-(4-fluoro-benz-yl)imino]-eth-yl}phenolato-?(2) N,O)palladium(II).

Project description:The asymmetric unit of the title complex, [Pd(C15H13FNO)2], contains one half of the mol-ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd-N and Pd-O bond lengths of 2.028?(2) and 1.9770?(18)?Å, respectively. The fluoro-phenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2?(2)° with the phenolate ring. In the crystal, mol-ecules are linked into chains along the [101] direction by weak C-H?O hydrogen bonds. Weak ?-? inter-actions with centroid-centroid distances of 4.079?(2)?Å stack the mol-ecules along c.

| S-EPMC4438801 | biostudies-literature

Bis[2-(benzyl-imino-meth-yl)-4-chloro-phenolato-?N,O]nickel(II).

Project description:In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0?(2)°. No significant hydrogen bonding or ?-? stacking inter-actions are observed.

| S-EPMC2915132 | biostudies-literature

Bis{2,4-dibromo-6-[(2-phenyl-eth-yl)imino-meth-yl]phenolato-?N,O}cobalt(II).

Project description:In the title complex, [Co(C(15)H(12)Br(2)NO)(2)], the Co(II) atom is four-coordinated by two N,O-bidentate chelate Schiff base ligands, displaying a flattened tetra-hedral coordination environment. The Co(II) atom occupies a special position on a twofold rotation axis. In the crystal, mol-ecules are linked via weak C-H?Br inter-actions.

| S-EPMC3247558 | biostudies-literature

Bis{4-bromo-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}nickel(II) monohydrate.

Project description:The title mononuclear nickel complex, [Ni(C(9)H(9)BrNO(2))(2)]·H(2)O, was obtained by the reaction of 5-bromo-salicyl-aldehyde, 2-amino-ethanol and nickel nitrate in methanol. The Ni(II) atom is six-coordinated by two phenolate O, two imine N and two hy-droxy O atoms from two crystallographically different Schiff base ligands, forming an octa-hedral geometry. In the crystal, mol-ecules are linked by inter-molecular O-H?O and O-H?Br hydrogen bonds, forming a three-dimensional network.

| S-EPMC3200792 | biostudies-literature

Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).

Project description:In the title compound, [Pd(C(15)H(13)FNO(2))(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phen-oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the Pd(II) atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03?(6)°. The mol-ecular structure is stabilized by an intra-molecular C-H?O hydrogen bond. In the crystal, weak inter-molecular C-H?? inter-actions occur.

| S-EPMC3120330 | biostudies-literature

Bis{?-2-[1-(pyridin-2-yl-methyl-imino)-eth-yl]phenolato}bis-(azido-zinc).

Project description:The title compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], is a phenolate-bridged centrosymmetric dinuclear zinc(II) complex. The Zn?Zn distance is 3.076?(1)?Å. Each Zn atom is five-coordinated by two O and two N atoms from two Schiff base ligands, and by one azide N atom, forming a square-pyramidal geometry.

| S-EPMC3247522 | biostudies-literature

Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-?N,O}cobalt(II).

Project description:In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8?(3)°].

| S-EPMC2959770 | biostudies-literature

Chlorido{?-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-?-oxido-dicopper(II) trihydrate.

Project description:In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H?Cl hydrogen bonds while O-H?O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

| S-EPMC3379123 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data