Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Poly[[[?(3)-N'-(carboxymethyl)ethylene-di-amine-N,N,N'-triacetato]dysprosium(III)] trihydrate].

ABSTRACT: In the title coordination polymer, {[Dy(C(10)H(13)N(2)O(8))]·3H(2)O}(n), the dysprosium(III) ion is coordinated by two N atoms and six O atoms from three different (carb-oxy-meth-yl)ethyl-ene-diamine-triacetate ligands in a distorted square-anti-prismatic geometry. The ligands connect the metal atoms, forming layers parallel to the ab plane. O-H?O hydrogen bonds further assemble adjacent layers into a three-dimensional supra-molecular network.

SUBMITTER: Zhuang X

PROVIDER: S-EPMC3009363 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Poly[[[μ(3)-N'-(carboxymethyl)ethylene-di-amine-N,N,N'-triacetato]dysprosium(III)] trihydrate].

Zhuang Xiaomei X Long Qingping Q Wang Jun J

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

In the title coordination polymer, {[Dy(C(10)H(13)N(2)O(8))]·3H(2)O}(n), the dysprosium(III) ion is coordinated by two N atoms and six O atoms from three different (carb-oxy-meth-yl)ethyl-ene-diamine-triacetate ligands in a distorted square-anti-prismatic geometry. The ligands connect the metal atoms, forming layers parallel to the ab plane. O-H⋯O hydrogen bonds further assemble adjacent layers into a three-dimensional supra-molecular network. ...[more]

PMID: 21588859

Similar Datasets

Poly[[tetra-aqua-?(4)-fumarato-di-?(3)-fumarato-dineodymium(III)] trihydrate].

Project description:The title coordination polymer, {[Nd(2)(C(4)H(2)O(4))(3)(H(2)O)(4)]·3H(2)O}, was synthesized by the reaction of neodymium(III) nitrate hexa-hydrate with fumaric acid in a water-methanol (7:3) solution. The asymmetric unit comprises two Nd(3+) cations, three fumarate dianions (L(2-)), four aqua ligands and three uncoordinated water mol-ecules. The carboxyl-ate groups of the fumarate dianions exhibit different coordination modes. In one fumarate dianion, two carboxyl-ate groups chelate two Nd(3+) cations, while one of the O atoms is coordinated to another Nd(3+) cation. Another fumarate dianion bridges three Nd(3+) cations: one of the carboxyl-ate groups chelates one Nd(3+) cation, while the other carboxyl-ate group bridges two Nd(3+) cations in a monodentate mode. The third fumarate dianion bridges four Nd(3+) cations, where one of the carboxyl-ate groups chelates one Nd(3+) cation and coordinates in a monodentate mode to a second Nd(3+), while the second carboxyl-ate groups bridges two Nd(3+) cations in a monodentate mode and one O atom is coordinated to one Nd(3+) cation. The Nd(3+) cations are in a distorted tricapped-trigonal prismatic environment and coordinated by seven O atoms from the fumarate ligands and two O atoms from water mol-ecules. The Nd(3+) cations are linked by two carboxyl-ate O atoms and two carboxyl-ate groups, generating infinite Nd-O chains to form a three-dimensional framework. There are O-H?O and C-H?O hydrogen-bonding interactions between the coordin-ated and uncoordinated water mol-ecules and carboxyl-ate O atoms.

| S-EPMC3238635 | biostudies-literature

Poly[aqua-[?-N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetato]neodymium(III)].

Project description:In the title complex, [Nd(C(10)H(13)N(2)O(8))(H(2)O)](n), each Nd(III) ion is coordinated by six O atoms and two N atoms from one N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetate (edta) ligand and one water mol-ecule, displaying a bicapped trigonal-prismatic geometry. The edta ligands link the neodymium metal centres, forming polymeric chains running along the a axis of the unit cell. These chains are further assembled via inter-molecular O-H?O hydrogen-bonding inter-actions into a three-dimensional supra-molecular network.

| S-EPMC2960570 | biostudies-literature

Poly[?-5-ammonio-isophthalato-aqua-?-oxalato-dysprosium(III)].

Project description:The title complex, [Dy(C(8)H(6)NO(4))(C(2)O(4))(H(2)O)](n), is a dysprosium coordination polymer with mixed anions and was obtained under hydrothermal conditions. In the structure, the oxalate and 5-amino-isophthalate ligands link the dysprosium ions, building up a two-dimensional metal-organic framework parallel to the (10) plane. These sheets are further connected through O-H?O, N-H?O and C-H?O hydrogen bonds, forming a three-dimensional supra-molecular structure.

| S-EPMC2969203 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')dysprosium(III)] [molybdenum(VI)-di-?-sulfido-silver(I)-di-?-sulfido]].

Project description:Hexamethyl-phospho-ramide (hmp), tetra-thio-molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n-) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti-prismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo-Ag-Mo and Ag-Mo-Ag angles of 161.911?(13) and 154.014?(13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue.

| S-EPMC3009021 | biostudies-literature

Poly[dimethyl-ammonium [aquadi-?(2)-oxalato-dysprosate(III)] trihydrate].

Project description:The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydro-thermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic coordination sphere of the Dy(III) atom is completed by a water mol-ecule. The bridging mode of the anions results in the formation of a three-dimensional network with cavities where the ammonium cations and the uncoordinated water mol-ecules reside. The structure is stabilized by numerous N-H?O and O-H?O hydrogen-bonding inter-actions.

| S-EPMC3007264 | biostudies-literature

Triimidazolium tris-(pyridine-2,6-di-carboxyl-ato)dysprosate(III) trihydrate.

Project description:The structure of the title compound, (C(3)N(2)H(5))(3)[Dy(C(7)H(3)NO(4))(3)]·3H(2)O, contains a mononuclear Dy(III) complex with the rare earth metal cation in a distorted tricapped trigonal-prismatic environment. The Dy(III) ion is in each case O,N,O'-chelated by three tridentate pyridine-2,6-dicarboxyl-ate anions. Three protonated imidazole mol-ecules act as counter-cations and three lattice water mol-ecules are also present. Numerous N-H⋯O and O-H⋯O hydrogen bonding inter-actions, some of which are bifurcated, help to stabilize the packing of the structure.

| S-EPMC2983370 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Project description:Hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver sulfide and dysprosium nitrate were self-assembled, forming an anionic [AgWS(4)](n) (n) (-) chain in the title compound, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two didentate nitrate and four hmp ligands, giving rise to a distorted square anti-prismatic structure. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain, with W-Ag-W and Ag-W-Ag angles 161.16 (2) and 153.606 (11)°, respectively, presents a distorted linear configuration. The title compound is isotypic with other rare earth complexes.

| S-EPMC2983176 | biostudies-literature

Poly[dimethyl-ammonium [aquadi-μ(2)-oxalato-yttriate(III)] trihydrate].

Project description:The title complex, {(C(2)H(8)N)[Y(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained accidentally under hydro-thermal conditions. The Y(III) atom is chelated by four oxalate ligands and one water mol-ecule resulting in a distorted tricapped trigonal-prismatic geometry. Each oxalate ligand bridges two Y(III) atoms, thus generating a three-dimensional network with cavities in which the ammonium cations and lattice water mol-ecules reside. Various O-H⋯O and N-H⋯O hydrogen-bonding inter-actions stabilize the crystal structure. The title complex is isotypic with the Eu and Dy analogues.

| S-EPMC3151934 | biostudies-literature

Poly[[?(2)-acetato-aquadi-?(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate].

Project description:In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol-ecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water mol-ecules link the carboxyl-ate group and the acetate ligand by O-H?O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508?(12) and 0.492?(12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy.

| S-EPMC2972040 | biostudies-literature

catena-Poly[[[diacrylato-κO,O'-neodymium(III)]-di-μ-acrylato-κO,O':O';κO:O,O'-[triaqua-neodymium(III)]-di-μ-acrylato-κO,O':O';κO:O,O'] trihydrate].

Project description:The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro-thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water mol-ecules. Extensive hydrogen bonding between the coordinated and uncoordin-ated water mol-ecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network.

| S-EPMC2959831 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data