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Poly[bis-[?-1,4-bis-(1H-imidazol-5-yl)benzene-?N:N]diformatomanganese(II)].

ABSTRACT: In the title compound, [Mn(CHO(2))(2)(C(12)H(10)N(4))(2)](n), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octa-hedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn(II) atoms lying on a plane. The crystal structure is consolidated by inter-molecular N-H?O hydrogen bonds..

SUBMITTER: Chen SS

PROVIDER: S-EPMC3011459 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[bis-[μ-1,4-bis-(1H-imidazol-5-yl)benzene-κN:N]diformatomanganese(II)].

Chen Shui-Sheng SS Yang Sen-Lin SL Zhang Shu-Ping SP Lu Zi-Qiang ZQ

Acta crystallographica. Section E, Structure reports online 20101106 Pt 12

In the title compound, [Mn(CHO(2))(2)(C(12)H(10)N(4))(2)](n), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octa-hedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn(II) atoms lying o ...[more]

PMID: 21589210

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