Unknown

Dataset Information

0

Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')(formato-?O,O')(formato-?O)cobalt(II) monohydrate.

ABSTRACT: The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol-ecule hydrogen bonded to a lattice water mol-ecule. The Co(II) cation is in a distorted octa-hedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10-phenanthroline ligand and four O atoms. Two of these are from a chelating formate anion, one from a monodentate formate and the last from an aqua ligand. In the crystal, mol-ecules are connected by O-H?O hydrogen bonds, forming double chains along [100] with the 2,9-dimethyl-1,10-phenanthroline ligands pointing outwards from each chain. These chains are further linked into layers parallel to (011) by inter-chain ?-? stacking inter-actions with centroid-centroid distances of 3.61?(1)?Å.

SUBMITTER: Ni SL 

PROVIDER: S-EPMC3050392 | biostudies-other | 2010

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')(formato-κO,O')(formato-κO)cobalt(II) monohydrate.

Ni Sheng-Liang SL   Xia Ping P   Cao Feng F  

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol-ecule hydrogen bonded to a lattice water mol-ecule. The Co(II) cation is in a distorted octa-hedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10-phenanthroline ligand and four O atoms. Two of these are from a chelating formate anion, one from a monodentate formate and the last from an aqua ligand. In the crystal, mol-ecules are connected by O  ...[more]

Similar Datasets

Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')diformato-κO,O';κO-nickel(II) monohydrate.
| S-EPMC3200966 | biostudies-literature
Unknown Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).
| S-EPMC2983147 | biostudies-literature
Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(2-hydroxy-benzoato-?O)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate.
| S-EPMC2968132 | biostudies-literature
Unknown Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.
| S-EPMC3009208 | biostudies-literature
Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(3-hydroxy-benzoato-?O)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).
| S-EPMC2977455 | biostudies-literature
Unknown Bis(benzoato-?O,O')(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).
| S-EPMC2960282 | biostudies-literature
Unknown Aqua-(dicyanamido-?N)(2,9-dimethyl-1,10-phenanthroline-?N,N')(nitrato-?O,O')cobalt(II)-2,9-dimethyl-1,10-phenanthroline-water (2/1/2).
| S-EPMC3201307 | biostudies-other
Unknown A second polymorph of aqua-(2,9-di-methyl-1,10-phenanthroline-κN,N')bis-(formato-κO)copper(II).
| S-EPMC2961975 | biostudies-literature
Unknown Dichlorido(2,9-dimethyl-1,10-phenanthroline)manganese(II) hemihydrate.
| S-EPMC2971941 | biostudies-literature
Unknown Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')copper(II).
| S-EPMC2970365 | biostudies-literature